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Towards a phenomenological definition of the term ‘gel’

Profile image of Søren HvidtSøren Hvidt

1993, Polymer Gels and Networks

https://doi.org/10.1016/0966-7822(93)90020-I
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Abstract

The term 'gel' is used so indiscriminately that it has become ambiguous. Existing definitions are reviewed, examples of unfortunate uses of the term are discussed, and important phenomenological characteristics of gels are identified. We propose that the term 'gel' should be limited to systems which fulfil the following phenomenological characteristics: (a) they consist of two or more components one of which is a liquid, present in substantial quantity and (b) they are soft, solid, or solid-like materials. We further propose a definition of the solid-like characteristics of gels in terms of the dynamic mechanical properties, viz. a storage modulus, G'(to), which exhibits a pronounced plateau extending to times at least of the order of seconds and a loss modulus, G"(to), which is considerably smaller than the storage modulus in the plateau region.

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