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isotope separation

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lightbulbAbout this topic
Isotope separation is the process of concentrating specific isotopes of an element by exploiting differences in their physical or chemical properties. This technique is essential in various applications, including nuclear energy production, medical diagnostics, and scientific research, enabling the production of isotopes for specific uses.
lightbulbAbout this topic
Isotope separation is the process of concentrating specific isotopes of an element by exploiting differences in their physical or chemical properties. This technique is essential in various applications, including nuclear energy production, medical diagnostics, and scientific research, enabling the production of isotopes for specific uses.

Key research themes

1. How can nuclear reaction-based methods enhance the microanalysis and separation of stable oxygen isotopes?

This research area explores innovative nuclear reaction methodologies for analyzing and separating stable oxygen isotopes (notably 18O), focusing on overcoming limitations posed by the short half-lives of oxygen radioisotopes and challenges in mass spectrometry of thin oxide films. These approaches are critical for applications in surface reaction studies, materials science, and ultrapure material analysis, where precise isotopic characterization at microgram or submicrogram scales is required.

Key finding: Developed a method employing nuclear reactions such as 18O(p,α)15N and 18O(d,α)16N to detect very small quantities of stable oxygen isotopes in materials. The method addresses sensitivity limitations of mass spectrometry... Read more
Key finding: Proposed and implemented a remote monitoring system for controlling critical parameters (temperature in reactors, isotope concentrations, input flows) in an 18O isotope separation plant based on isotope exchange reactions... Read more
Key finding: Demonstrated that strontium isotopic ratios (90Sr/88Sr) in spent nuclear fuel particles remain consistent despite variable irradiations and isotopic compositions in other elements, offering a dependable isotopic tracer.... Read more

2. What advances enable rapid and integrated multi-element isotope separation from geological samples for high-precision mass spectrometry?

This theme focuses on the development of streamlined chemical separation techniques that isolate multiple key isotopic systems (e.g., Sr, Nd, Pb, Hf) from single rock digest samples. Such integrated approaches significantly reduce processing time and contamination risk, facilitating high-accuracy isotope ratio determinations essential for geochemical tracing, planetary differentiation studies, and isotope geochronology.

Key finding: Developed a tandem column separation procedure integrating Sr Spec and TODGA Spec resins to efficiently isolate Sr, Nd, Pb, and Hf fractions from a single geological sample dissolution. This method reduces the traditional... Read more
Key finding: Presented a fully automated technique enabling simultaneous high-precision determination of stable isotope ratios for carbon, nitrogen, and sulfur (13C/12C, 15N/14N, 34S/32S) from a single small sample aliquot using a purge... Read more
Key finding: Developed a two-stage ion-exchange column chemistry protocol tailored for the chemical purification of titanium isotopes from iron-rich mineral matrices (e.g., rutile, ilmenite, titanomagnetite). The technique achieves... Read more

3. What potential do rotating plasma technologies and laser-assisted atomic sorting hold for innovative, scalable isotope separation processes?

Research on harnessing physical phenomena such as plasma rotation induced by magnetic fields and irreversible state changes triggered by photon scattering explores novel routes for efficient isotope and mass separation. These approaches address fundamental limitations of established isotope separation technologies (e.g., gaseous diffusion, ultracentrifuge) by promising scalability, higher throughput, and applicability across the periodic table with reduced infrastructure needs.

Key finding: Explored the theoretical foundation and potential of rotating plasma techniques, especially those driven by rotating magnetic fields, for large-scale isotope and mass separation. Analytical stability diagrams show how ion... Read more
Key finding: Proposed a scalable isotope separation method based on single-photon atomic sorting where an isotope-selective laser induces an irreversible alteration in the atom's magnetic moment within an atomic beam. Subsequently,... Read more
Key finding: Demonstrated a laser-assisted retarded condensation (SILARC) method utilizing multipass resonator cavities to extend the interaction length between infrared laser photons and boron-containing gas flows, thereby selectively... Read more

All papers in isotope separation

Helium is the second most abundant element in the Universe after hydrogen. Considerable resources of helium-3 isotope (He3) are located mostly outside the Earth. He3 is very important for science and industry, especially for airport... more
As demands on 3He are increasing and conventional 3He production through tritium decay is decreasing, alternative 3He production methods are becoming economically viable. One such possibility is to use entropy filters for extraction of... more
In the timeframe of approximately 2008 to 2013, Idaho National Laboratory (INL) refurbished and reconstructed two 90-degree sector isotope separators 1,2 . The first one completed was originally designated for stable isotope production... more
This paper reviews the membrane processes for the nuclear fusion fuel cycle—namely, the treatment of the plasma exhaust gases and the extraction of tritium from the breeding blankets. With respect to the traditional processes, the... more
Next-generation exotic beam facilities will offer several approaches to produce rare isotopes far from stability. One approach is Isotope Separation On-line, ISOL, which is the isotope production by interactions of light ion beams with... more
A laser-isotope-separation study of lithium has been performed with two-step excitation involving UV laser radiation and a visible tunable-diode laser. The method yields a high degree of selectivity by tuning the narrow-linewidth diode... more
In the paper we developed a separation model for a cryogenic distillation column of hydrogen and it's isotopes, deuterium and tritium. Using the law of mass diffusion for mixtures (deduced in the frame of elementary theory of transport... more
We recently demonstrated an original approach to highly selective laser isotope separation of carbon-13 that employs vibrational overtone pre-excitation of CF 3 H together with infrared multiphoton dissociation [O.V. Boyarkin, M.... more
Idaho National Laboratory (INL) operates a mass separator that is currently producing high purity isotopes for use as internal standards for high precision isotope dilution mass spectrometry (IDMS). In 2008, INL began the revival of the... more
In the present work, we have suggested a technical solution of a CO laser facility for industrial separation of uranium used in the production of fuel for nuclear power plants. There has been used a method of laser isotope separation of... more
In a heterogeneous electrolyte system of a strongly basic anion exchanger and solutions of NaBF4 or NaClCO4 we established the influence of the nature and concentration of the eluent in chromatographic experiments on chlorine isotope... more
The photodissociation of the HD + molecular ion in intense short-pulsed linearly polarized laser fields is studied using a time-dependent wave-packet approach where molecular rotation is fully included. We show that applying a coherent... more
The photodissociation of the HD + molecular ion in intense short-pulsed linearly polarized laser fields is studied using a time-dependent wave-packet approach where molecular rotation is fully included. We show that applying a coherent... more
The photodissociation of the HD + molecular ion in intense short-pulsed linearly polarized laser fields is studied using a time-dependent wave-packet approach where molecular rotation is fully included. We show that applying a coherent... more
The photodissociation of the HD + molecular ion in intense short-pulsed linearly polarized laser fields is studied using a time-dependent wave-packet approach where molecular rotation is fully included. We show that applying a coherent... more
A double focusing sector field mass filter used in Nier-Johnson geometry has been built in order to perform Kr isotope enrichment for 81 Kr and 85 Kr isotopes. The principle consists in implanting Kr + ions accelerated at 7 keV in Al... more
In the timeframe of approximately 2008 to 2013, Idaho National Laboratory (INL) refurbished and reconstructed two 90-degree sector isotope separators 1,2. The first one completed was originally designated for stable isotope production but... more
The equilibrium isotope effect in tin(U)-tin(IV) electron-exchange systems has been studied by a redox chromatography method using an anion-exchange resin. It was shown that the light isotopes are concentrated in tin(I1) preferably. The... more
We propose a novel and simple method for the laser isotope separation of 176Lu a precursor for the production of 177Lu medical isotope. The physics of the laser-atom interaction has been studied through the dynamics of the atomic level... more
We devise a novel mechanism of isotope separation from a mixture of Bose-Einstein condensate in the presence of interspecies interaction. Fractional revivals of this miscible system are studied inside a ring waveguide for spatially... more
225Ac is a radio-isotope that can be linked to biological vector molecules to treat certain distributed cancers using targeted alpha therapy. However, developing 225Ac-labelled radiopharmaceuticals remains a challenge due to the supply... more
Experiments are undertaken on the isotope separation by DC discharge through a narrow capillary of gaseous neon, argon and krypton of natural isotopic abundance. It is confirmed that the heavier isotopes become enriched in the region of... more
We examine the kinetics of recombination in a weakly ionized, dilute, monatomic gas which is adiabatically expanding into vacuum. The hydrodynamic equations are solved exactly assuming; steady supersonic flow, maximal symmetry (isotropy),... more
An original approach to the time behavior of an isotope-separator-on-line production system is proposed in the case of a production system where the target and the ion source are connected through a conductance much larger than that of... more
The ability to separate large volumes of mixed species based on atomic mass appears desirable for a variety of emerging applications with high societal impact. One possibility to meet this objective consists in leveraging mass... more
We studied laser isotope separation of cesium (Cs) on the basis of a laser photochemical reaction and two-photon excitation scheme using a narrow line width Ti:sapphire laser to reduce long-term radioactive toxicity of a long-lived... more
Several improvements are described for the existing tritium enrichment system at the Isotope Hydrology Laboratory of the International Atomic Energy Agency for processing natural water samples. The improvements include a simple method for... more
The principal isotope enrichment business in the world is the enrichment of uranium for commercial power reactor fuels. However, there are a number of other needs for separated isotopes. Some examples are: 1) Pure isotopic targets for... more
The aim of this work was to investigate efficiency of the electrolytic separation of hydrogen isotopes (D/H), from alkaline 6 M KOH solution as standard electrolyte, on the Mo-Pt intermetallic phases as cathode materials. We measured the... more
This work describes the atomic laser isotope separation (LIS). The (LIS) plant means calculating the values of a large number of parameters in order to optimize some objective function. Here we use simple model to describe the elementary... more
Nowadays, cobalt isotopes 55Co, 57Co, and 58mCo are considered to be promising radionuclides in nuclear medicine, with 55Co receiving the most attention as an isotope for diagnostics by positron emission tomography. One of the current... more
A simple system of CARS (Coherent Anti-STOKES RAMAN Spectroscopy) was constructed and applied to measurements of the distribution of the concentration of hydrogen in a hydrogenair diffusion flame. The apparatus is similar to that used by... more
As demands on 3He are increasing and conventional 3He production through tritium decay is decreasing, alternative 3He production methods are becoming economically viable. One such possibility is to use entropy filters for extraction of... more
An experiment was undertaken on the isotopic separation by DC cataphoresis of neon gas of natural isotopic abundance, which proved through analysis of gas sampled after stabilization that the heavier isotope "Ne became enriched in the... more
The multiple photon dissociation of ppm level CTC13 in CDC13 and the selectivity of T/D separation were investigated using a pulsed ammonia laser. The effect of laser frequency, fluence and buffer gas pressure on the dissociation rate and... more
IR laser chemistry of (CF3Br/C12) mixture and neat CF2HCI are examined in the context of 13 C enrichment. Decomposition extent, enrichment factor and energy absorbed are measured for both systems at their respective optimum conditions. A... more
Hydrogen isotope separation based on differences in quantum zero-point energy was investigated using a novel temperature-programmed desorption approach. Spectra obtained as a function of hydrogen concentration reveal multiple distinct... more
Isotopes separation technologies are used in both Tritium Removal Facilities associated with CANDU reactors (to remove tritium from heavy water) and fusion applications (eq. ITER Isotope Separation System) to recover and enrich tritium... more
When uranyl nitrate is photolysed in the water solution, light isotope ${}^{235}{\rm U}$ is separated from isotope ${}^{238}{\rm U}$ ; an enrichment factor $K = 1.04$ . The initial samples were depleted by a light isotope of uranium... more
The efficiency of 13 C isotope separation by multiphoton dissociation using a CO 2 laser has been shown to increase by ~ 33 % upon addition of small amounts of HI to the starting mixture. The reason for this increase is that the CF 3... more
A self-developing gas chromatography (SDGC) process using a column packed with Pd-4 at.% Pt alloy powder was studied for hydrogen isotope separation at room temperature. Separation experiments of a deuterium-tritium (50% D 2-50% T 2)... more
The advantage of a red-shifted laser source in furthering the obtainable enrichment factor by laser assisted aerodynamic separation process has been reported. The enhancement owes its origin to the efficient multi-photon excitation... more
Isotopes of heavier gases including carbon (13C/14C), nitrogen (13N), and oxygen (18O) are highly important because they can be substituted for naturally occurring atoms without significantly perturbing the biochemical properties of the... more
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