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Structure, mineralogy and dynamics of the lowermost mantle

Profile image of Brandon ShimBrandon Shim

2010, Mineralogy and Petrology

https://doi.org/10.1007/S00710-009-0068-Z
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19 pages

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Abstract

The 2004-discovery of the post-perovskite transition initiated a vigorous effort in high-pressure, high-temperature mineralogy and mineral physics, seismology and geodynamics aimed at an improved understanding of the structure and dynamics of the D"-zone. The phase transitions in basaltic and peridotitic lithologies under pT-conditions of the lowermost mantle can explain a series of previously enigmatic seismic discontinuities. Some of the other seismic properties of the lowermost mantle are also consistent with the changes in physical properties related to the perovskite (pv) to post-perovskite (ppv) transition. After more than 25 years of seismic tomography, the lowermost mantle structure involving the sub-Pacific and sub-African Large Low Shear-Velocity Provinces (LLSVPs) has become a robust feature. The two large antipodal LLSVPs are surrounded by wide zones of high Vs under the regions characterized by Mesozoic to recent subduction. The D" is further characterized by a negative correlation between shear and bulk sound velocity which could be partly related to an uneven distribution of pv and ppv. Ppv has higher VS and lower \( V_{\Phi } \) (bulk sound speed) than pv and may be present in thicker layers in the colder regions of D". Seismic observations and geodynamic modelling indicate relatively steep and sharp boundaries of the 200-500 km thick LLSVPs. These features, as well as independent evidence for their long-term stability, indicate that they are intrinsically denser than the surrounding mantle. Mineral physics data demonstrate that basaltic lithologies are denser than peridotite throughout the lowermost mantle and undergo incremental densification due to the pvppv- transition at slightly shallower levels than peridotite. The density contrasts may facilitate the partial separation and accumulation of basaltic patches and slivers at the margins of the thermochemical piles (LLSVPs). The slopes of these relatively steep margins towards the adjacent horizontal core-mantle boundary (CMB) constitute a curved (concave) thermal boundary layer, favourable for the episodic generation of large mantle plumes. Reconstruction of the original positions of large igneous provinces formed during the last 300 Ma, using a paleomagnetic global reference frame, indicates that nearly all of them erupted above the margins of the LLSVPs. Fe/Mg-partitioning between pv, ppv and ferropericlase (fp) is important for the phase and density relations of the lower mantle. Electronic spin transition of Fe2+ and Fe3+ in the different phases may influence the Fe/Mg-partitioning and the radiative thermal conductivity in the lowermost mantle. The experimental determination of the \( {K_D}{^{Fe/Mg}_{pv/fp}}\left[ { = {{\left( {Fe/Mg} \right)}_{pv}}/{{\left( {Fe/Mg} \right)}_{fp}}} \right] \) and \( {K_D}{^{Fe/Mg}_{ppv/fp}} \) is technologically challenging. Most studies have found a \( {K_D}{^{Fe/Mg}_{pv/fp}} \) of 0.1-0.3 and a higher Fe/Mg-ratio in ppv than in pv. The experimental temperature is important, with the partitioning approaching unity with increasing temperature. Although charge-coupled substitutions of the trivalent cations Al and Fe3+ seem to be important in both pv and ppv (especially in basaltic compositions), the complicating crystal-chemistry effects of these cations are not fully clarified. The two anti-podal thermochemical piles as well as the thin ultra-low velocity zones next to the CMB may represent geochemically enriched reservoirs that have remained largely isolated from the convecting mantle through a major part of Earth history. The existence of such “hidden” reservoirs have previously been suggested in order to account for the imbalance between the inferred composition of the geochemically accessible convecting mantle and the observed heat flow from the Earth and chondritic models for the bulk Earth.

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A generalized inverse method is applied to infer the radial lower mantle composition and temperature profile from seismological models of density and bulk sound velocity. The computations are performed for a five-component system, MgO-FeO-CaO-Al 2 O 3 -SiO 2 and three phases: (Mg,Fe,Al)(Si,Al)O 3 perovskite, (Mg,Fe)O magnesiowustite, and CaSiO 3 perovskite. A detailed review of the elasticity data set used to compute the elastic properties of mineral assemblages is given. We consider three different a priori compositional models-pyrolite, chondritic and a model based on cosmic abundances of elements-as a priori knowledge for the inversions in order to investigate the sensitivity of any given best-fit solution to the assumed initial composition. Consistent features in all inversions, independent of the a priori model, are a total iron content of X Fe 0.10 ± 0.06 and a subadiabatic temperature gradient over most of the lower mantle depth range. A peculiar correlated behaviour of the two most sensitive parameters (iron content and temperature) is found below the 660 km discontinuity: over the depth range from 660 km down to 1300 km. Significantly, we find that the bulk composition inferred from any given inversion is strongly dependent on the choice of a priori model. Equally satisfactory fits to the lower mantle bulk sound velocity and density profiles can be obtained using any of the a priori models. However, the thermal structure associated with these compositional models differs significantly. Pyrolite yields a relatively cool geotherm (T 660 1800 K and X Pv 0.64), while perovskite-rich models such as chondritic or cosmic models yield hot geotherms (T 660 2500 K and X Pv 0.84 for the latter), but all of the geotherms are subadiabatic. The results of inversions are virtually unaffected by the partitioning of iron between perovskite and magnesiowustite. Out of the five oxide components considered in our models, the bulk Al 2 O 3 and CaO contents of the mineral assemblages are least well constrained from our inversions. Our results show that a major shortcoming of lower mantle compositional and thermal models based on inversions of bulk sound velocity and density is the strong dependence of the final solution on the a priori model. That is, a wide variety of best-fit compositional and thermal models can be obtained, all of which provide satisfactory fits to global average seismic models. It is, in fact, this non-uniqueness that dominates the resulting a posteriori uncertainties and prevents a clear discrimination between different compositional models. Independent constraints on the thermal structure or on the shear properties of lower mantle assemblages are needed to infer lower mantle composition with a higher degree of certainty.

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Influence of the post-perovskite transition on thermal and thermo-chemical mantle convection
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Chemistry of the Lower Mantle
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Two large low-shear-velocity provinces (LLSVPs) in the deep mantle beneath Africa and the Pacific are generally interpreted as hot but chemically dense 'piles', which have remained isolated from mantle circulation for several hundred million years. This interpretation largely hinges on four seismic observations: (i) their shear wave velocity anomalies are considered too large for purely thermal structures; (ii) shear wave velocity gradients at their edges are sharp; (iii) their shear to compressional wave-speed anomaly ratios are high; and (iv) their shear and bulk-sound velocity anomalies appear to be anti-correlated. However, using compressible global mantle circulation models driven by 300 Myr of plate motion history and thermodynamic methods for converting from physical to seismic structure, we show that observed lower mantle shear wave velocity anomalies do not require, and are most likely incompatible with, large-scale chemical 'piles'. A prescribed core-mantle-boundary temperature of 4000 K, which is consistent with current estimates, combined with anelastic seismic sensitivity to temperature, ensures that purely thermal LLSVPs, strongly focussed beneath Africa and the Pacific by subduction history, can reconcile observed shear wave velocity anomalies and gradients. By contrast, shear wave velocity anomalies from models that include dense chemical 'piles' at the base of Earth's mantle, where 'piles' correspond to only 3% of the mantle's volume, are substantially stronger than the tomographic model S40RTS, even after accounting for limited tomographic resolution. Our results also suggest that in the presence of post-perovskite, elevated ratios between shear and compressional wavespeed anomalies and the correlation between shear and bulk-sound velocity anomalies cannot be used to discriminate between thermal and compositional heterogeneity at depth: in all calculations, an anticorrelation only occurs within the post-perovskite stability field. Taken together, this implies that although there must be considerable chemical heterogeneity within Earth's mantle, large, coherent 'piles' are not required to reconcile the seismic observations examined here. Indeed, our results suggest that if chemical heterogeneity is present in these regions, its dynamical and seismic significance is far less than has previously been inferred.

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Thermochemical interpretation of 1-D seismic data for the lower mantle: The significance of nonadiabatic thermal gradients and compositional heterogeneity
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Journal of Geophysical Research, 2009

1] Equation-of-state (EOS) modeling, whereby the seismic properties of a specified thermochemical structure are constructed from mineral physics constraints, and compared with global seismic data, provides a potentially powerful tool for distinguishing between plausible mantle structures. However, previous such studies at lower mantle depths have been hampered by insufficient evaluation of mineral physics uncertainties, overestimation of seismic uncertainties, or biases in the type of seismic and/or mineral physics data used. This has led to a wide, often conflicting, variety of models being proposed for the average lower mantle structure. In this study, we perform a thorough reassessment of mineral physics and seismic data uncertainties. Uncertainties in both the type of EOS, and mineral elastic parameters, used are taken into account. From this analysis, it is evident that the seismic variability due to these uncertainties is predominantly controlled by only a small subset of the mineral parameters. Furthermore, although adiabatic pyrolite cannot be ruled out completely, it is problematic to explain seismic velocities and gradients at all depth intervals with such a structure, especially in the interval 1660-2000 km. We therefore consider a range of alternative thermal and chemical structures, and map out the sensitivity of average seismic velocities and gradients to deviations in temperature and composition. Compositional sensitivity is tested both in terms of plausible end-member compositions (e.g., MORB, chondrite), and via changes in each of the five major mantle oxides, SiO 2 , MgO, FeO, CaO, and Al 2 O 3 . Fe enrichment reduces both P and S velocities significantly, while Si enrichment (and Mg depletion) increases P and S velocities, with a larger increase in P than in S. Using purely thermal deviations from adiabatic pyrolite, it remains difficult to explain simultaneously all seismic observations. A superadiabatic temperature gradient does improve the seismic fit in the lowermost mantle, but should be accompanied by concurrent bulk chemistry changes. Our results suggest that the most plausible way to alter bulk chemistry in the lowermost mantle, simultaneously fitting density, bulk velocity and shear velocity constraints, is an increasing contribution of a hot, basalt-enriched component with depth. Citation: Cobden, L., S. Goes, M. Ravenna, E. Styles, F. Cammarano, K. Gallagher, and J. A. D. Connolly (2009), Thermochemical interpretation of 1-D seismic data for the lower mantle: The significance of nonadiabatic thermal gradients and compositional heterogeneity,

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