Center provided essential assistance with sample analysis and database management. James Kingsbur... more Center provided essential assistance with sample analysis and database management. James Kingsbury, Bruce Lindsey, and Laura Bexfield of the USGS National Water Quality Program-Groundwater Assessments Project provided permission to describe and use results from sequential samples collected from the same wells and their associated data.
the final quantile positions of the eggs and larvae beyond the downstream model domain are unknow... more the final quantile positions of the eggs and larvae beyond the downstream model domain are unknown, the outcomes still provide useful information about conditions favorable to spawning and recruitment habitat for bighead carp in the Ohio River.
Iron and steel slags from legacy and modern operations in the Chicago-Gary area of Illinois and I... more Iron and steel slags from legacy and modern operations in the Chicago-Gary area of Illinois and Indiana, USA, are predominantly composed of Ca (10–44 wt. % CaO), Fe (0.3–28 wt. % FeO), and Si (10–44 wt. % SiO2), with generally lesser amounts of Al (<1–15 wt. % Al2O3), Mg (2–11 wt. % MgO), and Mn (0.3–9 wt. % MnO). Mineralogy is dominated by Ca ± Mg ± Al silicates, Fe ± Ca oxides, Ca-carbonates, and high-temperature SiO2 phases. Chromium and Mn concentrations in most samples may be environmentally significant based on comparison with generic soil contaminant guidelines. However, simulated weathering tests suggest these elements are present in generally insoluble phases making their use in water treatment applications possible; however, the generation of high pH and alkaline solutions may be an issue. As for possible water treatment applications, batch and flow-through experiments document effective removal of phosphate from synthetic solutions for nearly all slag samples. Air-cool...
Tertiary-treated wastewater currently (1991) is being injected into the Hueco bolson aquifer at a... more Tertiary-treated wastewater currently (1991) is being injected into the Hueco bolson aquifer at a site in northeastern El Paso, Texas, to supplement the quantity of available freshwater. Hydrologic data were compiled and water-quality and bacterial data were collected from existing wells near the Hueco Bolson Recharge Project (HBRP) in August and September 1990 and 1991. Borehole tracer tests indicated upward groundwater flow in nearly all tested intervals of several observation wells. The cumulative volume of injected water was less than the volume produced from wells adjacent to the HBRP area. Water levels in three production wells, located more than 1.5 miles from the injection wells, declined at rates comparable to those observed before injection operations. Water levels in wells located within 0.75 mile of the injection-well pipeline declined at a slower rate after HBRP injection operations had begun. Between 1985 and 1991, water levels in observation wells located within 700 feet of an injection well either did not appreciably decline, or declined at smaller rates than water levels in more distant production wells. Trihalomethane compounds were detected in water from 8 of the 16 observation and production wells sampled in 1990 and in 10 of the 17 wells sampled in 1991. Concentrations of trihalomethane compounds in these samples ranged from 0.05 to 1.9 |lg/L (micrograms per liter) in 1990 and from 0.05 to 1.4 |ig/L in 1991. Concentrations of trihalomethane compounds in samples of injected water from two wells were 27.8 and 34.6 |J,g/L respectively, in 1991. Dibromomethane and dichloromethane were detected in water from injection wells and from observation wells within about 700 feet of the injection wells. Aerobic bacteria were determined to be the only bacteria type present in ground water except for samples from two wells, which also contained denitrifying bacteria. The populations of aerobic bacteria determined in ground water ranged from 80 to more than 160,000 most probable number of organisms per milliliter of sample.
Examples of interpreting age dates of groundwater samples using the atmosphericmixing ratios of c... more Examples of interpreting age dates of groundwater samples using the atmosphericmixing ratios of chloroflurocarbon (CFC) compounds relative to piston-flow and binary-mixing models: A. CFC-11 and CFC-12 and B. CFC-113 and CFC-12 ..
Multiply By To obtain streams and shallow-aquifer water with brines from deep aquifers. Dissoluti... more Multiply By To obtain streams and shallow-aquifer water with brines from deep aquifers. Dissolution of halite or mixing with deep-aquifer water was the most common cause of increased salinity in 48.0 percent of 77 water samples from shallow aquifers, as classified using salt-norm analysis; the second most common cause was the weathering and dissolution of sulfur-bearing minerals. Mixing with water from soil-mineral dissolution was classified as the principal source of chloride in 28.4 percent of 67 water samples from shallow aquifers with nitrate determinations. Trace-species/chloride ratios indicated that mixing with water from deep aquifers in rocks of the Pennsylvanian System was the principal source of chloride in 24.4 percent of 45 shallowaquifer samples lacking nitrate determinations.
Graphs showing relations between (A) del sulfur-34 (δ 34 S) of dissolved sulfate and dissolved so... more Graphs showing relations between (A) del sulfur-34 (δ 34 S) of dissolved sulfate and dissolved solids concentration, (B) δ 34 S of dissolved sulfide and dissolved solids concentration, and (C) δ 34 S of dissolved sulfate minus δ 34 S of dissolved sulfide and estimated temperature in groundwater samples from the Edwards aquifer saline-water zone, south-central Texas .
In cooperation with the National Park Service, the U.S. Geological Survey investigated water qual... more In cooperation with the National Park Service, the U.S. Geological Survey investigated water quality of key water bodies at the Lincoln Boyhood National Memorial near Lincoln City in southwestern Indiana. The key water bodies were (1) a stock pond, representing possible nonpoint agricultural effects on water quality; (2) an ephemeral stream, representing the water quality of drainage from forested areas of the park; (3) parking-lot runoff, representing water quality related to roads and parking lots; (4) an unnamed ditch below the parking lot, representing the water quality of drainage from the parking lot and from an adjacent railroad track; and (5) Lincoln Spring, a historical groundwater source representing groundwater conditions near a former diesel-fuel-spill site along a rail line. Water samples were analyzed for pH, temperature, specific conductance, and dissolved oxygen and for concentrations of selected major ions and trace metals, nutrients, organic constituents, and Escherichia coli bacteria. Surface-water-quality data of water samples from the park represent baseline conditions for the area in relation to the data available from previous studies of area streams. Specificconductance values and concentrations of most major ions and various nutrients in surface-water samples from the park were smaller than those reported for samples collected in other USGS studies in areas adjacent to the park. Water-quality-management issues identified by this investigation include potentially impaired water quality from parking-lot runoff, unknown effects on surface-water quality from adjacent railroads, and the potential impairment of water quality in Lincoln Spring from human influences. Parking-lot runoff is a source of calcium, alkalinity, iron, lead, and organic carbon in the water samples from the unnamed ditch. Detection of small concentrations of petroleum hydrocarbons in water from Lincoln Spring could indicate residual contamination from a 1995 diesel-fuel spill and cleanup. The concentration of nitrite plus nitrate in water from Lincoln Spring was 16.5 milligrams per liter as nitrogen, greater than the State of Indiana standard for nitrate in drinking water (10 milligrams per liter as nitrogen). Lead concentrations in samples from the stock pond, parking-lot runoff, and the unnamed ditch exceeded the Indiana chronic aquatic criteria. 03304055 (Site 35) 03304055 (Site 35) of the Raccoon Creek Group (Gray and others, 1970). The Buffaloville Coal Member of the Brazil Formation, Raccoon Creek Group is at or near the land surface to the west and south of the park and possibly in the park (Gray and others, 1970).
15. Boron concentrations (A) greater than 400 micrograms per liter and (B) less than 200 microgra... more 15. Boron concentrations (A) greater than 400 micrograms per liter and (B) less than 200 micrograms per liter in relation to boron isotope composition in water samples from representative sources of boron in ground water and from wells with an unknown groundwater source near Beverly Shores, northwestern Indiana, 2004 ...
Hydrogeology, Ground-Water-Age Dating, Water Quality, and Vulnerability of Ground Water to Contamination in a Part of the Whitewater Valley Aquifer System near Richmond, Indiana, 2002-2003
Restoration of highly degraded urban coastal waters often requires large-scale, complex projects,... more Restoration of highly degraded urban coastal waters often requires large-scale, complex projects, but in the interim, smaller-scale efforts can provide immediate improvements to water quality conditions for visitor use. We examined short-term efforts to improve recreational water quality near the Grand Calumet River (GC) in the Laurentian Great Lakes. Identified as an Area of Concern (AOC) by the International Joint Commission, the GC has experienced years of industrial and municipal waste discharges, and as a result, coastal beaches have some of the highest rates of beach closings (>70%) in the United States. Project objectives were to identify sources of microbial contamination and to evaluate a short-term management solution to decrease beach closings: during 2015 (partial) and 2016 (season-long), canines were used to deter gull presence. Water samples were analyzed for in 2015 and 2016, and fecal sources were evaluated using microbial source tracking markers (2015): human ( H...
In a long-term evaluation of the injection of treated wastewater into an alluvial aquifer near El... more In a long-term evaluation of the injection of treated wastewater into an alluvial aquifer near El Paso, TX, the boron (8) concentration and B stable isotopic values were investigated as potential intrinsic tracers of recharge-water source. The B stable isotopic values (SllB) of background groundwater (14%0) and water from anthropogenic sources such as treated municipal wastewater (6-10%0) and irrigation-affected water (>40%0) were distinctly different. The B concentrations in combination with the B stable isotope values distinguished these water types and natural saline water as sources of recharge to groundwater. Boron is suited for use as a conservative tracer in groundwater because of its high solubility in aqueous solution (predominantly as boric acid), its natural presence in nearly all water, and the lack of effects by evaporation or volatilization, by oxidationreduction reactions, or by mineral precipitation or dissolution in all but extremely saline waters. The variability of any observed isotopic ratio in groundwater can be from several processes, such as variability in the B source, mixing, and partitioning reactions, including sorption, which cause isotopic fractionation. For rocks and minerals, a range in 611B values of more than 70%0 has been reported. Water sources sampled to date have a similarly broad range. In this injection test, B concentrations in all samples were below 1 mg/L, and differences between individual sources of salinity were indistinct based on analytical concentration alone. In contrast, a hypothetical, nonlinear mixture between solutions with different 611B values and different B concentrations demonstrated a detectable isotopic shift for small volume percent contributions of the source water with the largest boron concentration. The Hueco Bolson aquifer a t the injection site is geologically heterogeneous, and the free water surface is more than 90 m deep. The cost to establish a sufficient density of monitoring wells to describe the flow of injected water in groundwater is prohibitive. For this and other sites, chemical and isotopic tracers such as B and 6"B may be used to identify the influence of various water sources with potentially adverse environmental consequences.
A method has been developed to measure nanogram per liter amounts of selected volatile organic co... more A method has been developed to measure nanogram per liter amounts of selected volatile organic compounds (VOCs) including dichlorodifluoromethane, trichlorofluoromethane, cis-1,2-dichloroethene, trichloroethene, tetrachloroethene, and the isomers of dichlorobenzene in water. The method uses purge-and-trap techniques on a 100 mL sample, gas chromatography with a megabore capillary column, and electron impact, selected ion monitoring mass spectrometry. Minimum detection levels for these compounds ranged from 1 to 4 ng/L in water. Recoveries from organic-free distilled water and natural groundwater ranged from 70.5% for dichlorodifluoromethane to 107.8% for 1,4-dichlorobenzene. Precision was generally best for cis-1,2-dichloroethene, tetrachloroethene, and the dichlorobenzene isomers and worst for dichlorodinuoromethane and trichlorofluoromethane. Blank data indicated persistent, trace-level introduction of dichlorodifluoromethane, 1,4-dichlorobenzene, and tetrachloroethene to samples during storage and shipment at concentrations less than the method reporting l i m i t s. The largest concentrations of the selected VOCs in 27 water samples from the Edwards aquifer near San Antonio, 'lX, were from confined-zone wells near an abandoned landfill. The results defined a zone of water with no detectable VOCs in nearly all of the aquifer west of San Antonio and from part of the confined zone beneath San AntOniO. Studies in Europe and the United States have found an association between detections of volatile organic compounds (VOCs) in groundwater from unconfined aquifers and urban land
Per- and polyfluoroalkyl substances in groundwater from the Great Miami buried-valley aquifer, southwestern Ohio, 2019–20
U.S. Geological Survey Scientific Investigations Report 2023-5017, 2023
Groundwater samples were collected during 2019 and 2020 from 23 wells in the Great Miami buried-v... more Groundwater samples were collected during 2019 and 2020 from 23 wells in the Great Miami buried-valley aquifer (GM-BVA) in southwestern Ohio by the U.S. Geological Survey, in cooperation with the Miami Conservancy District, Dayton, Ohio, to determine concentrations of selected per- and polyfluoroalkyl substances (PFAS). The GM-BVA is a glacial outwash and alluvial fill aquifer that is the sole source of water supply for much of the region. Wells had total depths that ranged from 21 to 101 feet below land surface, and groundwater levels that ranged from 1.39 to 52.15 feet below land surface before sampling in 2019.
Groundwater and related quality-control samples were sequentially collected from 22 of the 23 wells and analyzed for 24 different PFAS by 2 methods that used proprietary isotope-dilution based adaptations of U.S. Environmental Protection Agency (EPA) method 537.1, termed methods 1 and 2. Method 2 had smaller reporting limits (RL) for 22 of 24 PFAS analyzed and smaller detection limits (DLs) for all 24 PFAS analyzed compared with method 1, which made method 2 more sensitive to detect PFAS.
Concentrations of perfluorooctanesulfonate (PFOS) in a groundwater (GW)-method 2 sample from well CL–275 of 1.9 nanograms per liter (ng/L) and perfluorooctanoate (PFOA) in a GW-method 2 sample from well BU–1106 of 2.1 ng/L were greater than their EPA interim health advisory guidances for drinking water (as of June 2022) by about 9,500 and 52,500 percent, respectively. The EPA interim health advisory guidances for PFOS (0.02 ng/L) and PFOA (0.004 ng/L) were also 65 and 215 times less, respectively, than the smallest method 2 DLs for PFOS (1.3 ng/L) and PFOA (0.86 ng/L).
Other PFAS were either not detected in GM-BVA groundwater samples or were detected in concentrations less than Ohio action levels or Federal health-risk-based guidance. The most detected PFAS in groundwater was perfluorobutanesulfonate (PFBS), which had concentrations in samples from eight wells that ranged from 1.0 to 8.0 ng/L or from 0.05 to 0.4 percent of its EPA health advisory of 2,000 ng/L for drinking water.
The similarity of PFBS (7.8 ng/L), perfluoropentanesulfonate (PFPeS; 8.1 ng/L), and perfluorohexanesulfonate (PFHxS; 14 ng/L) concentrations yielded from the GW-method 1 sample from well CL–275 on July 9, 2019, to those of PFBS (8.0 ng/L), PFPeS (7.8 ng/L), and PFHxS (16 ng/L) from the paired GW-method 2 sample demonstrated the capability of both methods to reproduce PFAS concentrations that were greater than their respective DLs. Non-detection of these PFAS in follow-up GW-method 1 and sequential replicate (Rep–GW-method 1) samples from CL–275 on April 21, 2020, indicated that the 2019 results represented a transient detection in groundwater.
Eleven of twenty-three wells sampled in 2019 had from 1 to 4 PFAS detected in one or more groundwater samples or in a paired replicate sample: PFBS in 8 wells and 9 samples; PFHxS in 4 wells and 5 samples; and PFPeS, PFOS, perfluorobutanoate, perfluoropentanoate, PFOA, and perfluorooctanesulfonamide in 1 well and 1 sample each. More PFAS were detected in GW-method 2 samples than GW-method 1 samples because method 2 had smaller RLs and DLs. Results indicate benefits from the analysis of paired samples, sequential replicate samples, and other quality-control samples using analytical methods with sensitive RLs and DLs to verify PFAS concentrations in groundwater.
Groundwater-age estimates indicate that water produced from all sampled wells had infiltrated to the water table within the 1947–present (2022) period of PFAS use or environmental presence. Eight wells with detectable PFBS in groundwater from 2019 samples also had groundwater-recharge dates that ranged from 1991 to 2016. Those ages coincided with the possible environmental presence of PFBS as a PFAS byproduct or use as an alternative to PFOS after about 2002. Two wells that had detections of PFHxS in 2019 groundwater samples also had post-2000 groundwater-recharge dates that coincided with the period of use of PFHxS as an alternative to PFOS. Six of nine wells with more than 66-percent of urban land use that was within 0.3 miles of each well, as of 2012, also had 1 to 4 PFAS detected in one of their groundwater samples. Seven of nine wells that produced groundwater in 2019 with an oxic redox category also had one or more PFAS detected in a sample.
Application of hydrogeology and groundwater-age estimates to assess the travel time of groundwater at the site of a landfill to the Mahomet Aquifer, near Clinton, Illinois
The effects of highway-deicer application on ground-water quality were studied at a site in north... more The effects of highway-deicer application on ground-water quality were studied at a site in northwestern Indiana using a variety of geochemical indicators. Site characteristics such as high snowfall rates; large quantities of applied deicers; presence of a high-traffic highway; a homogeneous, permeable, and unconfined aquifer; a shallow water table; a known ground-water-flow direction; and minimal potential for other sources of chloride and sodium to complicate source interpretation were used to select a study area where ground water was likely to be affected by deicer application. Forty-three monitoring wells were installed in an unconfined sand aquifer (the Calumet aquifer) near Beverly Shores in northwestern Indiana. Wells were installed along two transects that approximately paralleled groundwater flow in the Calumet aquifer and crossed US-12. US-12 is a highway that receives Indiana?s highest level of maintenance to maintain safe driving conditions. Ground-water quality and wat...
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Papers by Paul Buszka
Groundwater and related quality-control samples were sequentially collected from 22 of the 23 wells and analyzed for 24 different PFAS by 2 methods that used proprietary isotope-dilution based adaptations of U.S. Environmental Protection Agency (EPA) method 537.1, termed methods 1 and 2. Method 2 had smaller reporting limits (RL) for 22 of 24 PFAS analyzed and smaller detection limits (DLs) for all 24 PFAS analyzed compared with method 1, which made method 2 more sensitive to detect PFAS.
Concentrations of perfluorooctanesulfonate (PFOS) in a groundwater (GW)-method 2 sample from well CL–275 of 1.9 nanograms per liter (ng/L) and perfluorooctanoate (PFOA) in a GW-method 2 sample from well BU–1106 of 2.1 ng/L were greater than their EPA interim health advisory guidances for drinking water (as of June 2022) by about 9,500 and 52,500 percent, respectively. The EPA interim health advisory guidances for PFOS (0.02 ng/L) and PFOA (0.004 ng/L) were also 65 and 215 times less, respectively, than the smallest method 2 DLs for PFOS (1.3 ng/L) and PFOA (0.86 ng/L).
Other PFAS were either not detected in GM-BVA groundwater samples or were detected in concentrations less than Ohio action levels or Federal health-risk-based guidance. The most detected PFAS in groundwater was perfluorobutanesulfonate (PFBS), which had concentrations in samples from eight wells that ranged from 1.0 to 8.0 ng/L or from 0.05 to 0.4 percent of its EPA health advisory of 2,000 ng/L for drinking water.
The similarity of PFBS (7.8 ng/L), perfluoropentanesulfonate (PFPeS; 8.1 ng/L), and perfluorohexanesulfonate (PFHxS; 14 ng/L) concentrations yielded from the GW-method 1 sample from well CL–275 on July 9, 2019, to those of PFBS (8.0 ng/L), PFPeS (7.8 ng/L), and PFHxS (16 ng/L) from the paired GW-method 2 sample demonstrated the capability of both methods to reproduce PFAS concentrations that were greater than their respective DLs. Non-detection of these PFAS in follow-up GW-method 1 and sequential replicate (Rep–GW-method 1) samples from CL–275 on April 21, 2020, indicated that the 2019 results represented a transient detection in groundwater.
Eleven of twenty-three wells sampled in 2019 had from 1 to 4 PFAS detected in one or more groundwater samples or in a paired replicate sample: PFBS in 8 wells and 9 samples; PFHxS in 4 wells and 5 samples; and PFPeS, PFOS, perfluorobutanoate, perfluoropentanoate, PFOA, and perfluorooctanesulfonamide in 1 well and 1 sample each. More PFAS were detected in GW-method 2 samples than GW-method 1 samples because method 2 had smaller RLs and DLs. Results indicate benefits from the analysis of paired samples, sequential replicate samples, and other quality-control samples using analytical methods with sensitive RLs and DLs to verify PFAS concentrations in groundwater.
Groundwater-age estimates indicate that water produced from all sampled wells had infiltrated to the water table within the 1947–present (2022) period of PFAS use or environmental presence. Eight wells with detectable PFBS in groundwater from 2019 samples also had groundwater-recharge dates that ranged from 1991 to 2016. Those ages coincided with the possible environmental presence of PFBS as a PFAS byproduct or use as an alternative to PFOS after about 2002. Two wells that had detections of PFHxS in 2019 groundwater samples also had post-2000 groundwater-recharge dates that coincided with the period of use of PFHxS as an alternative to PFOS. Six of nine wells with more than 66-percent of urban land use that was within 0.3 miles of each well, as of 2012, also had 1 to 4 PFAS detected in one of their groundwater samples. Seven of nine wells that produced groundwater in 2019 with an oxic redox category also had one or more PFAS detected in a sample.