Thermal Analysis of Micro- and Nano-Lignocellulosic Reinforced Styrene Maleic Anhydride Composite Foams
International Journal of Polymer Analysis and Characterization, 2015
ABSTRACT The aim of this study was to measure the thermal properties of foamed nano/macro filler ... more ABSTRACT The aim of this study was to measure the thermal properties of foamed nano/macro filler reinforced styrene maleic anhydride (SMA) composites. SMA (66%) as a polymer matrix (10% maleic anhydride content) and various fillers including: wood flour, starch, α-cellulose, microcrystalline cellulose or cellulose nano fibrils as reinforcing agents (30%) and lubricant (4%) were used to manufacture the composites in twin screw extruder. Dynamic mechanical thermal analysis (DMTA) analysis was done to determine the viscoelastic properties and glass transition temperature (Tg) of the composite foams. The analysis of loss modulus (E'') allowed us to observe relaxation behavior of the foamed composites. Thermogravimetric analysis (TGA) was used to measure the thermal decomposition properties of the foamed composites. According to the TGA results, thermal degradation of all the foamed composites was found to be lower compared with pure SMA polymer composites. The storage modulus values were negatively affected with a second time foaming (re-processing (recycling) the initially processed composites a second time) and it can be said that same situation was similar for loss modulus and Tg, too. As results, second times foamed composite were lower than those of the foamed composites. According to the MFI test, viscosity of the SMA was found to be increase with the addition of fillers.
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Papers by Gokhan Gunduz
This study investigated the influence of untreated and heat treated wood fillers on the mechanical and rheological properties of wood filled nylon 6 composites for possible under-the-hood applications in the automobile industry where conditions are too severe for commodity plastics to withstand. In this study, exposure of wood to high temperatures (212 C for 8 h) improved the thermal stability and crystallinity of wood. Heat treated pine and maple filled nylon 6 composites (at 20 wt.% loading) had higher tensile strengths among all formulations and increased tensile strength by 109% and 106% compared to neat nylon 6, respectively. Flexural modulus of elasticity (FMOE) of the neat nylon 6 was 2.34 GPa. The FMOE increased by 101% and 82% with the addition of 30 wt.% heat treated pine and 20 wt.% heat treated maple, where it reached maximum values of 4.71 GPa and 4.27 GPa, respectively. The rheological properties of the composites correlated with the crystallinity of wood fillers after the heat treatment. Wood fillers with high crystallinity after heat treatment contributed to a higher storage modulus, complex viscosity
and steady shear viscosity and low loss factor in the composites. This result suggests that heat treatment substantially affects the mechanical and rheological properties of wood filled nylon 6 composites. The mechanical properties and thermogravimetric analysis indicated that the heat treated wood did not show significant thermal degradation under 250 �C, suggesting that the wood-filled nylon composites could be especially relevant in thermally challenging areas such as the manufacture of under-the-hood automobile components.
species with low density wood is preferred to obtain lightweight structures in arrow shafts. High elasticity module supports increase of bending strength for arrow shaft which is already slender and fragile. Arrow lengths tend to vary between 60 cm and 80 cm while arrow masses range between 9 gr and 50 gr arrows could be classified by material but it would not be accurate because each part of arrow consisted by different material. As arrows shafts may be sorted as wooden and bamboo, arrow classes can be sorted as war, field, target, flight, and practice and contest arrows. Ottomans named arrow sections anthropologically. Arrow shaft is divided into 24
equal sections. First 4 sections from nock towards point named as head, the section where head ends is called neck, the 11. section is called belly, sections between neck and belly are called chest, sections between belly and 17. section are called calf, sections between calf and point are called foot. Turkish archers have great records in flight shooting. There is a record that measures 845.5 m and still is not beaten with similar equipment.
Keywords: Arrow, Bow, Wood, Turkish Arrow Construction.