Effect of aggregates containing iron sulphide on asphalt ageing

2013

This paper presents an extensive review of the pertinent literature regarding asphalt and asphalt mixture Aging. Aging affects flexible pavement performance and is produced by intrinsic and extrinsic variables as well as exposure time. Intrinsic variables include asphalt and aggregate properties, a mixture's asphalt content, binder film thickness and air void content; extrinsic variables are associated with production (short-term aging) and exposure to environmental field conditions (long-term aging). Taken together, both variables demonstrate that aging results from three distinct mechanisms: volatilisation, oxidation and steric hardening. Temperature, pressure and photo degradation treatments are used to simulate aging in the laboratory and empirical and semi-empirical models are created to represent and study aging. Aging increases asphalt complex modulus and decreases the phase angle. Mixtures become stiffer while fatigue life becomes reduced. Carbonyl and sulfoxide group formation in asphalt are often studied as such chemical changes show oxidation in aged asphalts. The prevailing models used to predict asphalt aging are discussed, though more comprehensive research into asphalt aging is still needed.

Advances and Applications in Statistics, 2018

In the design of asphalt paving mixtures, aggregates from the stockpiles are blended at selected proportions to satisfy specified gradation ranges. In a laboratory environment, the mix designer controls the proportion from each stockpile so that the proportions (or weights) can be assumed fixed. This is unlike in a plant operation where aggregates are fed from bins into a mixing-drum so that the Saeed Maghsoodloo, Randy West and Dilcu Barnes 428 proportion of each aggregate, from each bin is a random variable. Statistical analyses of the former case are well-known and are first repeated in Sections 2 and 3. The objective of this article is to provide statistical information for the case when aggregate proportions are treated as random variables. The formulas in Section 4 provide the reader with a method of calculating approximate first two moments of asphalt paving mixture characteristic treated as random variables witnessed in plant operations.

Road Materials and Pavement Design, 2017

Ageing of asphalt mixtures occurs during production and construction and continues throughout the service life of the pavement. Although this topic has been studied extensively, recent changes in asphalt mixture components, production parameters, and plant design have raised a need for a comprehensive evaluation that considers the impacts of climate, aggregate type, recycled materials, WMA technology, plant type, and production temperature. In this study, field cores were acquired from seven field projects at construction and several months afterwards, and raw materials were also collected for fabricating laboratory specimens that were long-term oven aged (LTOA) in accordance with selected protocols. The resilient modulus and Hamburg wheel tracking tests were conducted on both specimen types to evaluate the evolution of mixture stiffness and rutting resistance with ageing. The concepts of cumulative degree days and mixture property ratio were proposed to quantify field ageing and its effect on mixture properties. Test results indicated that the LTOA protocols of two weeks at 140°F (60°C) and five days at 185°F (85°C) produced mixtures with equivalent in-service field ageing of 7-12 months and 12-23 months, respectively, depending on climate. Finally, among the factors investigated in the study, WMA technology, recycled materials, and aggregate absorption exhibited a significant effect on the long-term ageing characteristics of asphalt mixtures, while production temperature and plant type had no effect.

This paper presents an extensive review of the pertinent literature regarding asphalt and asphalt mixture Aging. Aging affects flexible pavement performance and is produced by intrinsic and extrinsic variables as well as exposure time. Intrinsic variables include asphalt and aggregate properties, a mixture's asphalt content, binder film thickness and air void content; extrinsic variables are associated with production (short-term aging) and exposure to environmental field conditions (long-term aging). Taken together, both variables demonstrate that aging results from three distinct mechanisms: volatilisation, oxidation and steric hardening. Temperature, pressure and photo degradation treatments are used to simulate aging in the laboratory and empirical and semi-empirical models are created to represent and study aging. Aging increases asphalt complex modulus and decreases the phase angle. Mixtures become stiffer while fatigue life becomes reduced. Carbonyl and sulfoxide group formation in asphalt are often studied as such chemical changes show oxidation in aged asphalts. The prevailing models used to predict asphalt aging are discussed, though more comprehensive research into asphalt aging is still needed.

Revista Ingenieria E Investigacion, 2013

This paper presents an extensive review of the pertinent literature regarding asphalt and asphalt mixture Aging. Aging affects flexible pavement performance and is produced by intrinsic and extrinsic variables as well as exposure time. Intrinsic variables include asphalt and aggregate properties, a mixture's asphalt content, binder film thickness and air void content; extrinsic variables are associated with production (short-term aging) and exposure to environmental field conditions (long-term aging). Taken together, both variables demonstrate that aging results from three distinct mechanisms: volatilisation, oxidation and steric hardening. Temperature, pressure and photo degradation treatments are used to simulate aging in the laboratory and empirical and semi-empirical models are created to represent and study aging. Aging increases asphalt complex modulus and decreases the phase angle. Mixtures become stiffer while fatigue life becomes reduced. Carbonyl and sulfoxide group formation in asphalt are often studied as such chemical changes show oxidation in aged asphalts. The prevailing models used to predict asphalt aging are discussed, though more comprehensive research into asphalt aging is still needed.

2000

In response to the need to improve asphalt pavement performance, the Strategic Highway Research Program (SHRP) was initiated in 1987. Products from SHRP included performance-based specifications for asphalt binders and performance-based mix design tests and criteria for asphalt mixtures. The Superpave asphalt binder specification addresses performance of in-service pavements for given environmental and traffic conditions. During the 1985 paving season in Indiana, the original asphalt binder and HMA (truck mix samples) from a number of pavements were sampled and retained. Cores were also taken from these pavements after seven or eight years of service. Condition surveys were performed on these pavements, prior to coring. The study objectives were directed toward characterizing the original and extracted/recovered asphalt binders from the field samples using Superpave test methods and equipment. Taking this approach provided an early opportunity to examine a number of features of the Superpave system, including short (RTFO) and long-term (PAV) aging. Results of this research documented the difference in stiffness between RTFO aged and asphalts extracted and recovered from loose mixtures; in addition to, the difference in stiffness between PAV aged and in-service aged asphalts, in Indiana. Additionally, asphalt stiffness was related to pavement performance. A poor relationship was found between the stiffness of RTFO aged asphalts and rutting. On the other hand, a good relationship was found between stiffness of in-service asphalts and cracking. Collected weather data from seven counties indicated agreement between calculated PG grades for these counties and recommended Superpave PG grade, based on the environmental conditions. Based on the results of this research, recommendations were made to further investigate the short-and long-term binder aging to better address variability and reliability of these procedures, to address storage conditions sometimes unavoidable for field samples, and to validate PG grades requirements for Indiana.

Applied Sciences, 2019

Asphalt mixtures are subjected to short-term aging during the production, placement, and compaction processes. Proper evaluation of asphalt pavement performance relies on the accurate characterization of asphalt mixtures during the design stage. In this study, three different loose asphalt mixtures often used in Qatar were evaluated to develop a laboratory short-term aging procedure. Sample mixtures 1 and 3 were collected from a construction site, while mixture 2 was obtained from an asphalt plant. Virgin aggregates and binders were also collected to reproduce the mixtures in the laboratory. Laboratory-produced mixtures were conditioned at 135 °C using various time durations. The mechanical properties of laboratory-produced mixtures were compared to those of mixtures produced on site. The results of the mechanical and binder testing demonstrated that the proper short-term aging protocol for asphalt mixtures often used in road construction in the State of Qatar would involve heating ...

Materials and Structures, 2013

The main objective of this study is to investigate the influence that asphalt mixture morphology aspects have on its overall ageing behavior. Since mixture morphology is controllable, having insight into how the various morphological parameters influence the mixture's long-term behavior can be of great value to optimize its design, regardless of the individual material properties. To do so, this study is utilizing a new framework to characterize the combined effect of aggregate packing, average air void size, porosity and level of compaction on ageing for a large set of data from different sources of field compacted and laboratory produced asphalt mixtures. The paper also hypothesizes about the mechanisms that lay behind the found influences and how thus mixture design improvements can be made. From all the investigated cases, it was found that the framework can be used to optimize the durability performance of asphalt mixtures. It was also observed that prediction of ageing behavior without considering the influence of mixture morphology may lead to erroneous conclusions and non-optimal mix design.

HAL (Le Centre pour la Communication Scientifique Directe), 2012

Aging of asphalt binders leads to damage on pavements, due to changes in their rheological behavior and in the binder composition. A hardening of the asphalt can be observed, mainly caused by the oxidation of the asphalt binder itself. Oxidation rate is influenced by temperature, ultraviolet radiation and intrinsic characteristics of materials. In order to be characterized, the binder is extracted from the field-aged asphalt cores that use to have several centimetres in thickness. The aging process, however, depends on the access of oxygen into the field core which varies with the distance from the pavement surface. In order to know the aging conditions of the pavement surface (only) and to evaluate their influence on the adhesion characteristics, it is necessary to recover the surface asphalt binder. Only the surface binder is exposed to ultraviolet rays and weathering. A new test method has been developed in this work. It is based on the asphalt binder recovery from the upper part of the asphalt mixture layer. This method was validated by the infrared spectrometry through comparison with the neat asphalt binder (aged and not aged) and with the conventional extraction. In addition, an accelerated aging protocol was developed with the use of a climate chamber comprised of brightness settings, and moisture and weather conditioning, to relate to the French climate. The aging results obtained in the laboratory and in the field were compared using the same test method. This comparison allowed the establishment of an accelerator factor with respect to the increase of sulfoxide and carboxyl groups. This study provides a better understanding of the influence of aging on the skid resistance and the ability of the material to resist to polishing.

Road Materials and Pavement Design, 2014

Aging of asphalt binders leads to damage on pavements, due to changes in their rheological behavior and in the binder composition. A hardening of the asphalt can be observed, mainly caused by the oxidation of the asphalt binder itself. Oxidation rate is influenced by temperature, ultraviolet radiation and intrinsic characteristics of materials. In order to be characterized, the binder is extracted from the field-aged asphalt cores that use to have several centimetres in thickness. The aging process, however, depends on the access of oxygen into the field core which varies with the distance from the pavement surface. In order to know the aging conditions of the pavement surface (only) and to evaluate their influence on the adhesion characteristics, it is necessary to recover the surface asphalt binder. Only the surface binder is exposed to ultraviolet rays and weathering. A new test method has been developed in this work. It is based on the asphalt binder recovery from the upper part of the asphalt mixture layer. This method was validated by the infrared spectrometry through comparison with the neat asphalt binder (aged and not aged) and with the conventional extraction. In addition, an accelerated aging protocol was developed with the use of a climate chamber comprised of brightness settings, and moisture and weather conditioning, to relate to the French climate. The aging results obtained in the laboratory and in the field were compared using the same test method. This comparison allowed the establishment of an accelerator factor with respect to the increase of sulfoxide and carboxyl groups. This study provides a better understanding of the influence of aging on the skid resistance and the ability of the material to resist to polishing.