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Introduction
Synthesis Methods
Design and Morphology
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Chemistry
Catalysis

MOFs in carbon capture-past, present and future

Profile image of Benjaram M ReddyBenjaram M Reddy
https://doi.org/10.1016/J.JCOU.2020.101297
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Abstract

Metal Organic Frame works (MOFs) are being widely used in carbon capture through adsorption and membrane techniques, which are yet to be commercialized. This is due to their high affinity towards acidic gases and exceptional characteristics such as crystallinity, structural stability, high surface area and flexible pore dimensions. In this review, wide range of topics viz., synthesis protocols, modifications employed to further improve their attributes, comprehensive comparison of different MOFs used in carbon capture, thermo-kinetics modelling studies, contactors and material screening. Every section has been discussed in detail in terms of developmental trends, future challenges and prospects besides summarizing in the form of comprehensive tables at a glance for the benefit of the readers. Solvo-thermal method was found to be the most effective synthesis method besides ultra-sonication and microwave assisted methods, which also gave very good crystalline structures. The copper ligand based unmodified Cu-BTC MOF gave the maximum CO 2 uptake value of 9.59 mmol/g at 273 K and 1 atm. Zn(Bmic)(AT) MOF was the only species to be tested at 353 K. Alternatively, a photo-responsive MOF, Mg-IRMOF-74-III functionalized with azopyridine gave a CO 2 uptake of 89 cc/g which is comparable to many of the conventional MOFs. Kinetics indicate MOF adsorption mostly follows pseudo second order reactions either along with Toth isotherms or modified Langmuir isotherms. Fixed and fluidized bed reactors perform the best in terms of carbon capture studies. Moisture affinity, active sites and crystallinity were found to be the best factors considered whilst screening of proper MOFs. Abbreviations: CC, Carbon dioxide Capture; SA, Surface area; PV, Pore volume; DMF, N,N-Dimethylformamide; mmol/g, millimoles of CO 2 per gram of adsorbent; cc/g, cubic centimeters of CO 2 per gram of adsorbent; CLC, Chemical Looping Combustion.

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    Qasem Delavar

    Materials Today Communications

    This paper used sodium hydroxide to improve the CO 2 adsorption capacity of coal-based activated carbon. The effect of several modification parameters, including sodium hydroxide concentration (0.01-8 M), impregnation time (4-7 h), drying duration (4-7 h), the effect of washing, and the impact of fixed bed operating conditions such as inlet flow rate, the height of the adsorption column, and operating pressure on CO 2 adsorption capacity were investigated. The plain and impregnated adsorbents were thoroughly characterized by several instrumental analyses. With increasing NaOH loading, CO 2 adsorption capacity improved until its maximum value at 1 M NaOH concentration. Washing the samples was an important parameter on CO 2 uptake in the fixed bed when samples were impregnated with high concentration NaOH solution. The mechanisms of modification and CO 2 adsorption process on the modified activated carbon were carefully studied. The dynamic adsorption capacity for the plain and impregnated AC at optimum conditions were 21.20 and 51.41 mg/g, respectively, which indicates that the capacity for CO 2 adsorption increased by more than 142%. According to the findings, NaOH-modified activated carbon can efficiently capture CO 2 .

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    Selective adsorption of volatile organic compounds in metal-organic frameworks (MOFs)
    Tanya Hutter

    Coordination Chemistry Reviews, 2023

    Results concerning the adsorption capacity of aluminum methylphosphonate polymorph alpha (AlMePO-R) for pure ethyl chloride and vinyl chloride by measured individual adsorption isotherms of these pure compounds are presented and discussed here. The experimental data supports the idea of using these materials as selective adsorbents for separating these compounds in mixtures. To explore this possibility further, we have performed grand canonical Monte Carlo simulations using a recently proposed molecular simulation framework for gas adsorption on AlMePO, and the results are presented here. The molecular model of the material was used in a purely transferable manner from a previous work (

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    A Lamellar Zn-Based Coordination Polymer Showing Increasing Photoluminescence upon Dehydration
    Antonio Luque

    Molecules

    The present study reports on a 2D lamellar coordination polymer (CP) of {[Zn(µ3-pmdc)(H2O)]·H2O}n formula (pmdc = pyrimidine-4,6-dicarboxylate). This CP is synthesized under an appropriate acid-base reaction between the gently mortared reagents in the solid state through a solvent-free procedure that avoids the presence of concomitant byproducts. The X-ray crystal structure reveals the occurrence of Zn2 entities connected through carboxylate groups of pmdc, which behave as triconnected nodes, giving rise to six-membered ring-based layers that are piled up through hydrogen bonding interactions. In addition to a routine physico-chemical characterization, the thermal evolution of the compound has been studied by combining thermogravimetric and thermodiffractometric data. The photoluminescence properties are characterized in the solid state and the processes governing the spectra are described using time-dependent density-functional theory (TD-DFT) with two different approaches employin...

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