1 Is Entropy Associated with Time ' s Arrow ?
2017
Abstract
We start with reviewing the origin of the idea that entropy and the Second Law are associated with the Arrow of Time. We then introduced a new definition of entropy based on Shannon’s Measure of Information (SMI). The SMI may be defined on any probability distribution; and therefore it is a very general concept. On the other hand entropy is defined on a very special set of probability distributions. More specifically the entropy of a thermodynamic system is related the probability distribution of locations and velocities (or momenta) of all the particles, which maximized the Shannon Measure of Information. As such, entropy is not a function of time. We also show that the H-function, as defined by Boltzmann is an SMI but not entropy. Therefore, while the H-function, as an SMI may change with time, Entropy, as a limit of the SMI does not change with time.
References (50)
- To reserve and use the concept of entropy only to macroscopic systems at equilibrium, and to use the concept of SMI for all other systems; small or large number of particles, near or far from equilibrium. References
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