Singularities in the Hamiltonian at electronic degeneracies
2000, Chemical Physics
https://doi.org/10.1016/S0301-0104(00)00202-0Abstract
We discuss the singularities which arise in the Hamiltonian operator at a crossing seam involving two potential energy surfaces of the same global symmetry. The Mead±Truhlar and our own equations are discussed and found to dier from each other, although leading to identical phases up to a constant factor and sign in the vicinity of the crossing seam. Also established are the relations which link the vector and scalar gauge potentials with the mixing angle.
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