Oyster shells, bulk carbonate sediment, and meteoric calcite cement as recorders of oceanic and radiogenic 87Sr/86Sr in mixed heterozoan carbonates and terrigenous sediment
Journal of Sedimentary Research, 2022
Well-preserved oyster shells from mixed heterozoan carbonates and terrigenous sediments of Miocen... more Well-preserved oyster shells from mixed heterozoan carbonates and terrigenous sediments of Miocene age in the La Chanata area (southern Spain) show varying luminescence and covarying δ18O and δ13C compositions > –2‰ VPDB. Temperature and salinity modeling based on the δ18O give temperatures ranging from 13 to 33 °C (average 22.4 °C) and normal-marine salinities (34–37 PSU). The isotopic compositions likely reflect environmental conditions during shell secretion; moreover, their identical intra-shell 87Sr/86Sr compositions (equal to or less than the analytical precision of 20 × 10–6) support a primary origin. Additional information from δ18O and 87Sr/86Sr compositions of Heterostegina foraminifera and sediment and cement samples show that: a) bulk sediment and cement samples that have significantly lower δ18O and δ13C values but 87Sr/86Sr values similar to the oyster shells likely derived their isotopic compositions from intraformational dissolution of high-Mg calcite and aragonit...
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