Free Energy, Exergy, and Energy: The Exergetic Content of Energy
A Treatise of Heat and Energy, 2019
Kelvin had introduced the general idea of available energy. The advent of the entropy principle l... more Kelvin had introduced the general idea of available energy. The advent of the entropy principle led to, in quick succession, the formulation of equilibrium thermodynamics by Gibbs—which was the prized fruit of the Kelvin–Clausius synthesis. One of its important results was the concept of free energies, which provided the general idea of available energies with specific examples—especially the Gibbs free energy of electrochemical energy→electrical work. Further development of available energy has evolved into the theory of exergy. Significantly, both the first law and the theory of exergy can be formulated for an engineering device’s control volume. In that formulation, the exergy treatment is reducible to the Carnot–Kelvin formula, a key tool in mechanical engineering, as well as to the Gibbs free energy, a key tool in chemical engineering.
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